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Facile synthesis of polypyrrole coated graphene Gr/Ag–Ag2O/PPy nanocomposites for a rapid and selective response towards ammonia sensing at room temperature
Journal of Science: Advanced Materials and Devices ( IF 7.382 ) Pub Date : 2021-02-16 , DOI: 10.1016/j.jsamd.2021.02.003
Mohd Shoeb , Mohammad Mobin , Sharique Ahmad , Alim H. Naqvi

This work demonstrates the fabrication of a highly selective ammonia (NH3) gas sensor based on Graphene/Silver–Silver Oxide/Polypyyrole (Gr/Ag–Ag2O/PPy) nanocomposite. To archive this objective, a cost-effective, room temperature mediated solution-based synthesis of Gr/Ag–Ag2O/PPy nanocomposite was exploited as an efficient performance NH3 gas sensor through combining the exceptional electrical characteristics of Graphene and sensing abilities of Ag–Ag2O/PPy. The as-synthesized nanomaterials were examined for relative DC conductivity with ammonia vapors' exposure at room temperature (25 °C) with the electrical signals' changes. The incorporation of Gr/Ag–Ag2O in PPy revealed about 40 times higher amplitude of conductivity change as compared to pristine PPy on exposure to the ammonia vapors. The reversibility response of Gr/Ag–Ag2O/PPy regarding the DC electrical conductivity with an effective variation range from 9.15 S/cm to 6.48 S/cm was observed in the ambient air on exposure to 1000 ppm of ammonia vapors. Gr/Ag–Ag2O/PPy was shown to offer a more excellent selectivity toward ammonia due to its basicity compared to different volatile organic compounds.



中文翻译:

简便地合成聚吡咯涂层的石墨烯Gr / Ag-Ag 2 O / PPy纳米复合材料,可在室温下对氨感测进行快速而选择性的响应

这项工作演示了基于石墨烯/银-氧化银/聚吡咯(Gr / Ag-Ag 2 O / PPy)纳米复合材料的高选择性氨(NH 3)气体传感器的制造。为了实现这一目标,通过结合石墨烯的出色电学特性和传感器的感应能力,开发了一种经济高效的室温介导的基于溶液的Gr / Ag-Ag 2 O / PPy纳米复合材料合成方法,作为一种高效能的NH 3气体传感器。 Ag–Ag 2 O / PPy。在室温(25°C)下,随着电信号的变化,对合成后的纳米材料的相对直流电导率进行了检测,同时氨气暴露在其中。Gr / Ag–Ag 2的掺入与原始PPy接触氨气后,PPy中的O显示出电导率变化幅度是原始PPy的约40倍。在暴露于1000 ppm氨蒸汽的环境空气中,观察到了Gr / Ag–Ag 2 O / PPy关于直流电导率的可逆性响应,其有效变化范围为9.15 S / cm至6.48 S / cm。与不同的挥发性有机化合物相比,由于其碱性,Gr / Ag-Ag 2 O / PPy具有更好的氨选择性。

更新日期:2021-02-16
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