As part of our ongoing search for high-performance nanoenergetic materials, we herein used self-assembly guided by negatively charged graphene oxide (GO) to fabricate a high-energy Al/GO/CuFe₂O₄ nanocomposite with a dense layered structure featuring evenly mixed Al and CuFe₂O₄ nanoparticles uniformly loaded on the GO surface. Investigation of the effects of the equivalence ratio (Φ ​= ​1.00–1.75) showed that the heat release achieved at the optimal value of Φ ​= ​1.50 (3175 ​± ​65 ​J·g⁻¹) exceeded that of most known thermites, while the fierce ignition process of this composite was characterized by an ignition delay time of (0.025 ​± ​0.002) s, a flame propagation speed of (14.3 ​± ​3.8) m·s⁻¹, and a continuous reaction duration of (33 ​± ​0.58) ms. In addition, the nanocomposite with Φ ​= ​1.00 effectively catalyzed the thermal decomposition of 1,3,5-trinitroperhydro-1,3,5-triazine (RDX) and ammonium perchlorate (AP), decreasing their decomposition temperatures by 7.4 and 64.8 ​°C, respectively, reducing their apparent activation energies of decomposition by 118.7 and 18 ​kJ·mol⁻¹, respectively. And the constant-volume combustion enthalpies of RDX and AP increase with the addition of Al/GO/CuFe₂O₄. The reason of this enhanced performance was probed by analyzing the nanocomposite assembly process, and a plausible assembly mechanism was proposed.

作为我们不断寻求的高性能纳米能量材料的一部分，我们在本文中使用了带负电的氧化石墨烯（GO）引导的自组装技术，以制造出高能量的Al / GO / CuFe ₂ O ₄纳米复合材料，该复合材料具有均匀分布的致密层状结构混合的Al和CuFe ₂ O ₄纳米颗粒均匀地负载在GO表面上。对当量比（Φ  = 1.00-1.75）的影响的研究表明，在Φ  = 1.50（3175±65 J·g ^-1）的最佳值下实现了放热）超过了最著名的铝热剂，而这种复合材料的剧烈着火过程的特征在于着火延迟时间为（0.025±0.002）s，火焰传播速度为（14.3±3.8）m·s ^-1且连续反应持续时间为（33±0.58）ms。此外，Φ  = 1.00的纳米复合材料可有效催化1,3,5-三硝基过氢-1,3,5-三嗪（RDX）和高氯酸铵（AP）的热分解，将其分解温度降低7.4和64.8 °C分别将其表观分解活化能分别降低118.7和18 kJ·mol ^-1。随着Al / GO / CuFe ₂ O ₄的加入，RDX和AP的等体积燃烧焓增加。。通过分析纳米复合材料组装过程探讨了这种性能提高的原因，并提出了合理的组装机理。