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Atmospheric chemistry of CF3C≡CCF3: Kinetics, products, mechanism of gas-phase reaction with OH radicals, and atmospheric implications
Atmospheric Environment ( IF 5 ) Pub Date : 2021-02-13 , DOI: 10.1016/j.atmosenv.2021.118264
Qiyan Zhang , Sheng Qin , Zhikai Guo , Hang Ni , Jianjun Zhang

The CF3CCCF3 reaction offers a potential alternative to greenhouse gas-producing reactions in a wide range of industrial applications; however, a better understanding of its impacts on the atmospheric environment is needed before it can be safely and effectively applied on a large scale. In this study, the rate constant (k1) for the reaction of CF3CCCF3 with OH was measured to be (7.28 ± 0.07) × 10−14 by the relative rate method, and the Arrhenius expression was k1 (253–328 K) = (1.53 ± 0.44) × 10−12 exp[–(906 ± 97)/T] cm3 molecule−1 s−1. The atmospheric lifetime of CF3CCCF3 was estimated to be 159 d, while its radiative efficiency was determined to be 0.250 Wm−2 ppb−1. The 20-, 100-, and 500-year global warming potentials of CF3CCCF3 were estimated to be 152, 41, and 12, respectively. What's more, the photochemical ozone creation potentials of CF3CCCF3 were estimated to be 0.50 and 0.13 for northwestern European conditions and US urban conditions, respectively. Hence, its contribution to the formation of tropospheric ozone is negligible. What's more, CF3OOOCF3, COF2, and CO2 were identified as carbon-containing products following the degradation of CF3CCCF3. Our results confirm that there is no secondary environmental pollution following the degradation of CF3CCCF3. Hence, the findings show that CF3Ctriple bondCCF3 is a substitute with relatively low environmental impact.



中文翻译:

CF 3 C的大气化学CCF 3:动力学,产物,与OH自由基进行气相反应的机理以及对大气的影响

CF 3 CCCF 3反应可在许多工业应用中替代温室气体产生反应;但是,在安全,有效地大规模应用之前,需要更好地了解其对大气环境的影响。在这项研究中,CF 3 C反应的速率常数(k 1相对速率法测得含OH的CCF 3为(7.28±0.07)×10 -14,Arrhenius表达式为k 1(253–328 K)=(1.53±0.44)×10 -12 exp [-( 906±97)/ T] cm 3分子-1  s -1。CF 3 C的大气寿命CCF 3被估计为159 d,而其辐射效率被确定为0.250 Wm -2  ppb -1。CF 3 C的20、100和500年全球变暖潜力CCF 3估计分别为152、41和12。此外,CF 3 C的光化学臭氧产生潜力欧洲西北部地区和美国城市地区的CCF 3估计分别为0.50和0.13。因此,它对对流层臭氧形成的贡献可忽略不计。此外,随着CF 3 C的降解,CF 3 OOOCF 3,COF 2和CO 2被确定为含碳产品。CCF 3。我们的结果证实,CF 3 C降解后不会造成二次环境污染CCF 3。因此,研究结果表明,CF 3 C 三键CCF 3是对环境影响较小的替代品。

更新日期:2021-02-24
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