Abstract

Addition polynorbornenes are the promising class of polymers for macromolecular design of various engineering polymers. This work has shown for the first time the fundamental possibility to obtain addition polynorbornenes in the presence of catalytic systems based on Pd(0) complexes activated by organic cocatalysts (aryl halides). Addition polymerization of norbornene has been studied in the presence of different cocatalysts, which allowed one to assess the effect of cocatalyst nature on the activity of the catalytic system.

中文翻译：

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基于Pd（0）配合物的降冰片烯加成聚合新催化体系

摘要

另外，聚降冰片烯是用于各种工程聚合物的大分子设计的有前途的聚合物。这项工作首次显示了在基于有机助催化剂（芳基卤化物）活化的Pd（0）络合物的催化体系存在下获得加成降冰片烯的基本可能性。已经在不同助催化剂存在下研究了降冰片烯的加成聚合反应，这使人们能够评估助催化剂性质对催化体系活性的影响。