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Photoredox Reaction of Naphthoquinone C‐Glycoside Revisited: Insight into Stereochemical Aspect
Helvetica Chimica Acta ( IF 1.8 ) Pub Date : 2021-02-04 , DOI: 10.1002/hlca.202100008 Yoshio Ando 1 , Takashi Matsumoto 1 , Keisuke Suzuki 1
Helvetica Chimica Acta ( IF 1.8 ) Pub Date : 2021-02-04 , DOI: 10.1002/hlca.202100008 Yoshio Ando 1 , Takashi Matsumoto 1 , Keisuke Suzuki 1
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Insights into the naphthoquinone photoredox reactions have been gained from the reactions of a C‐glycosyl naphthoquinone. The retentiveness comes from the balance of the lifetime of intermediary zwitterionic species relative to the conformational change to bring about the stereo‐mutating C−C bond rotation.
中文翻译:
萘醌C-糖苷的光氧化还原反应:立体化学方面的见解。
从C-糖基萘醌的反应中可以了解萘醌光氧化还原反应。保持力来自中间两性离子物种的寿命相对于构象变化的平衡,以引起立体突变的C-C键旋转。
更新日期:2021-03-10
中文翻译:
萘醌C-糖苷的光氧化还原反应:立体化学方面的见解。
从C-糖基萘醌的反应中可以了解萘醌光氧化还原反应。保持力来自中间两性离子物种的寿命相对于构象变化的平衡,以引起立体突变的C-C键旋转。