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Energy transfer and the anti-thermal quenching behavior of Sr8MgCe(PO4)7:Tb3+ for temperature sensing
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy ( IF 4.4 ) Pub Date : 2021-02-05 , DOI: 10.1016/j.saa.2021.119548
Yanyan Li , Yanyan Zhou , Xiang Li , Haoyang Wu , Lei Zhao , Wenjie Wang

Novel color-adjustable phosphors Sr8MgCe(PO4)7:Tb3+ were synthesized by the solid-state reaction method. The X-ray diffraction was used to characterize the phase formation. The host shows blue emission under 310 nm excitation, ascribed to the 5d-4f transitions of Ce3+, while Sr8MgCe(PO4)7:xTb3+ phosphors exhibit the emission band of Ce3+ as well as the characteristic lines of Tb3+ under 310 nm excitation. The color variation was observed as the concentration of Tb3+ changes. Moreover, the host sensitizes the emission of Tb3+ through the energy transfer process, and the mechanism is the dipole–dipole interaction. In addition, the emission of the host declines with the increase of the temperature while that of Tb3+ increases. This anti-thermal quenching behavior was interpreted by the configurational coordinate diagram. In addition, the temperature sensing behavior based on the emission peaks of the host and Tb was studied in the range 298–523 K, and the largest sensitivity is 0.379% K−1. The results indicate that Sr8MgCe(PO4)7:Tb3+ is an attractive color-tunable phosphor for solid state lighting and temperature sensing.



中文翻译:

用于温度传感的Sr 8 MgCe(PO 47:Tb 3+的能量转移和抗热猝灭行为

通过固相反应法合成了新型的颜色可调荧光粉Sr 8 MgCe(PO 47:Tb 3+。X射线衍射用于表征相形成。主体在310 nm激发下显示蓝色发射,归因于Ce 3+的5d-4f跃迁,而Sr 8 MgCe(PO 47x Tb 3+磷光体显示Ce 3+的发射带及其特性310 nm激发下的Tb 3+谱线。随着Tb 3+的浓度观察到颜色变化变化。此外,主体通过能量转移过程使Tb 3+的发射增敏,其机理是偶极-偶极相互作用。另外,主体的发射随着温度的升高而下降,而Tb 3+的发射则随着温度的升高而下降。这种抗热淬火行为由构型坐标图解释。此外,基于主体和Tb的发射峰的温度感测行为在298–523 K范围内进行了研究,最大灵敏度为0.379%K -1。结果表明,Sr 8 MgCe(PO 47:Tb 3+ 是一种用于固态照明和温度感应的有吸引力的颜色可调荧光粉。

更新日期:2021-02-15
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