当前位置: X-MOL 学术Plasm. Sci. tech. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
NO x storage and reduction assisted by non-thermal plasma over Co/Pt/Ba/γ-Al2O3 catalyst using CH4 as reductant
Plasma Science and Technology ( IF 1.7 ) Pub Date : 2021-01-29 , DOI: 10.1088/2058-6272/abd620
Tao ZHU 1, 2 , Xing ZHANG 1 , Nengjing YI 1 , Haibing LIU 3 , Zhenguo LI 4
Affiliation  

NO x storage and reduction (NSR) technology has been regarded as one of the most promising strategies for the removal of nitric oxides (NO x ) from lean-burn engines, and the potential of the plasma catalysis method for NO x reduction has been confirmed in the past few decades. This work reports the NSR of nitric oxide (NO) by combining non-thermal plasma (NTP) and Co/Pt/Ba/γ-Al2O3 (Co/PBA) catalyst using methane as a reductant. The experimental results reveal that the NO x conversion of NSR assisted by NTP is notably enhanced compared to the catalytic efficiency obtained from NSR in the range of 150 C–350 C, and NO x conversion of the 8% Co/PBA catalyst reaches 96.8% at 350 C. Oxygen (O2) has a significant effect on the removal of NO x , and the NO x conversion increases firstly and then decreases when the O2 concentration ranges from 2% to 10%. Water vapor reduces the NO x storage capacity of Co/PBA catalysts on account of the competition for adsorption sites on the surface of Co/PBA catalysts. There is a negative correlation between sulfur dioxide (SO2) and NO x conversion in the NTP system, and the 8% Co/PBA catalyst exhibits higher NO x conversion compared to other catalysts, which shows that Co has a certain SO2 resistance.



中文翻译:

NO X储存还原由非热等离子体在Co /铂/ BA辅助/ γ -Al 2 ö 3使用CH催化剂4作为还原剂

NO x存储和还原(NSR)技术已被视为从稀薄燃烧发动机中去除一氧化氮(NO x)的最有希望的策略之一,并且等离子体催化方法用于NO x还原的潜力已经得到证实。在过去的几十年中。这项工作通过使用甲烷作为还原剂,将非热等离子体(NTP)与Co / Pt / Ba / γ- Al 2 O 3(Co / PBA)催化剂相结合,报告了一氧化氮(NO)的NSR 。实验结果表明,该NO X通过NTP辅助NSR的转化效率显着提高相对于在150 C-350℃的范围内从NSR获得的催化效率,和NO X 8%Co / PBA催化剂在350℃时的转化率达到96.8%。氧气(O 2)对NO x的去除具有显着影响,当O 2浓度为2时,NO x的转化率先升高然后降低。%至10%。由于对Co / PBA催化剂表面上的吸附位的竞争,水蒸气降低了Co / PBA催化剂的NO x储存能力。NTP系统中的二氧化硫(SO 2)与NO x转化率之间呈负相关,并且8%Co / PBA催化剂比其他催化剂具有更高的NO x转化率,这表明Co具有一定的SO 2 反抗。

更新日期:2021-01-29
down
wechat
bug