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Arsenic‐Bridged Silafluorene and Germafluorene as a Novel Class of Mixed‐Heteroatom‐Bridged Heterofluorenes
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-01-27 , DOI: 10.1002/ejoc.202001644
Hiroshi Sasaki 1 , Ippei Akioka 1 , Hiroaki Imoto 1, 2 , Kensuke Naka 1, 2
Affiliation  

Arsenic‐bridged silafluorene and germafluorene were synthesized as a new class of mixed‐heteroatom‐bridged heterofluorenes. The arsenic atom promoted intersystem crossing due to the heavy‐atom effect to enhance phosphorescence.
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中文翻译:

砷桥接的硅芴和锗苯芴是一类新型的杂原子桥接的杂芴混合物

砷桥接的硅芴和germ芴被合成为一类新的混合杂原子桥接的杂芴。由于重原子效应,砷原子促进了系统间的穿越,从而增强了磷光。
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更新日期:2021-03-01
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