Solvophobic interaction promoted supramolecular helical assembly of building blocks of weak intermolecular halogen bonding,Chemical Communications

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Solvophobic interaction promoted supramolecular helical assembly of building blocks of weak intermolecular halogen bonding
Chemical Communications ( IF 4.9 ) Pub Date : 2021-1-13 , DOI: 10.1039/d0cc08041a
Xiaosheng Yan _{1,

2,

3,

4,

5} , Jinlian Cao _{1,

2,

3,

4,

5} , Yanhan Zhang _{1,

2,

3,

4,

5} , Peimin Weng _{1,

2,

3,

4,

5} , Daiyu Miao _{1,

2,

3,

4,

5} , Zhixing Zhao _{1,

2,

3,

4,

5} , Zhao Li _{1,

2,

3,

4,

5} , Yun-Bao Jiang _{1,

2,

3,

4,

5}

Affiliation

We report supramolecular helical assembly in water of β-turn structured bis(N-amidothioureas) containing Br-substitutes of moderate halogen bonding ability, promoted by stronger hydrophobic interaction. The helical polymers show an unusual negative nonlinear CD-ee dependence.

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