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Mechanochemical reactivity inhibited, prohibited and reversed by liquid additives: examples from crystal-form screens
Chemical Science ( IF 8.4 ) Pub Date : 2021-1-20 , DOI: 10.1039/d0sc05071g
Mihails Arhangelskis 1 , Dejan-Krešimir Bučar 2 , Simone Bordignon 3 , Michele R Chierotti 3 , Samuel A Stratford 4 , Dario Voinovich 5 , William Jones 4 , Dritan Hasa 5
Affiliation  

We demonstrate that liquid additives can exert inhibitive or prohibitive effects on the mechanochemical formation of multi-component molecular crystals, and report that certain additives unexpectedly prompt the dismantling of such solids into physical mixtures of their constituents. Computational methods were employed in an attempt to identify possible reasons for these previously unrecognised effects of liquid additives on mechanochemical transformations.

中文翻译:

液体添加剂抑制,禁止和逆转的机械化学反应性:结晶筛的实例

我们证明液体添加剂可以对多组分分子晶体的机械化学形成产生抑制或抑制作用,并报告某些添加剂出乎意料地促使此类固体分解成其成分的物理混合物。采用计算方法试图确定液体添加剂对机械化学转化的这些以前无法识别的影响的可能原因。
更新日期:2021-01-20
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