Here, a series of N-containing hyper-cross-linked polymers (HCPs) were synthesized from triphenylamine (TPA) or/and carbazole (Cz) monomers by one-step crosslinking reactions including Scholl coupling and solvent knitting Friedel-Crafts. Especially, the two reactions were also performed separately under adding both of TPA and Cz, and prepared HCP3 and HCP6. Notably, HCP1, HCP2, HCP3 prepared by Scholl coupling possessed better porosity with the Brunauer-Emmett-Teller (BET) surface areas (S_BET) of 199.9–534.5 m²/g and micropore volume (V_micro) of 0.088–0.24 cm³/g, while HCP4, HCP5, and HCP6 synthesized by solvent knitting Friedel-Crafts had inferior S_BET (10.8–34.8 m²/g) with meso/macroporous structure. In addition, these HCPs displayed high N contents, various morphologies, and different hydrophobicity. Interestingly, HCP1 ~ HCP3 exhibited high CO₂ uptake (104.7–116.3 mg/g) and acceptable CO₂/N₂ selectivity at 273 K and 1.0 bar, and large isosteric heat of adsorption (Q_st) (28.0–46.7 kJ/mol), while the HCP4 ~ HCP6 showed the larger I₂ vapor uptake (254.2–324.8 wt%) at 351 K and 1.0 bar than HCP1 ~ HCP3 (136.5–185.6 wt%). The results indicated the porosity especially microporosity played an important role on CO₂ capture, while the S_BET was not always the dominated factors for I₂ vapor adsorption due to the predominant chemical interaction by electrons transfer, and the chemical structure of polymer skeletons should make the large contribution. This work will develop multifunctional polymers prepared by the facile synthetic method, and make a promising adsorbents for CO₂ and iodine capture.

在此，通过三步胺交联反应（包括Scholl偶联和溶剂编织Friedel-Crafts），由三苯胺（TPA）或/和咔唑（Cz）单体合成了一系列含N的超交联聚合物（HCP）。特别地，在添加TPA和Cz的同时，还分别进行了两个反应，并制备了HCP3和HCP6。值得注意的是，通过Scholl偶联制备的HCP1，HCP2，HCP3具有更好的孔隙率，布鲁诺尔-埃米特-泰勒（BET）表面积（S _BET）为199.9-534.5 m ² / g，微孔体积（V _micro）为0.088-0.24 cm ³ / g，而溶剂编织Friedel-Crafts合成的HCP4，HCP5和HCP6的S _BET较差（10.8–34.8 m² / g），具有介观/宏观结构。此外，这些HCP表现出较高的N含量，各种形态和不同的疏水性。有趣的是，HCP1〜HCP3在273 K和1.0 bar下表现出高的CO ₂吸收（104.7–116.3 mg / g）和可接受的CO ₂ / N ₂选择性，以及大的等规吸附热（Q _st）（28.0–46.7 kJ / mol） ），而HCP4〜HCP6在351 K和1.0 bar下显示的I ₂蒸气吸收量（254.2–324.8 wt％）比HCP1〜HCP3（136.5–185.6 wt％）更大。结果表明，孔隙率（尤其是微孔率）在CO ₂捕获中起着重要作用，而S _BET并不总是I 2的主导因素。₂蒸气吸附是由于电子传递的主要化学相互作用，而聚合物骨架的化学结构应起很大作用。这项工作将开发通过简便的合成方法制备的多功能聚合物，并为CO ₂和碘的捕获提供有希望的吸附剂。