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Boron Reagents and Catalysts for the Functionalization of Strained Heterocycles
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2021-01-18 , DOI: 10.1002/adsc.202001493
MAURO PINESCHI 1
Affiliation  

The particular nature of boron compounds allows an ample modularity of their properties ranging from Lewis acids, C‐nucleophiles, B‐nucleophiles, or even conjunctive reagents for new synthetic manipulations. Moreover, the increasing demand for functionalized boron derivatives for pharmaceutical or material science applications requires the development of new synthetic methods for boron introduction in organic compounds. This review summarizes the possible combinations of boron derivatives with a variety of strained heterocycles reported in the most recent literature.

中文翻译:

用于应变杂环官能化的硼试剂和催化剂

硼化合物的特殊性质使其特性具有足够的模块化性,包括路易斯酸,C-亲核试剂,B-亲核试剂,甚至是用于新的合成操作的混合试剂。此外,对用于药物或材料科学应用的功能化硼衍生物的需求不断增长,要求开发用于将硼引入有机化合物的新的合成方法。这篇综述总结了硼衍生物与最新文献中报道的各种应变杂环的可能组合。
更新日期:2021-01-18
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