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Magnetic organic polymer gel decorating Ag3PO4 as Z-scheme photocatalyst for water decontamination
Colloids and Surfaces A: Physicochemical and Engineering Aspects ( IF 5.2 ) Pub Date : 2021-01-18 , DOI: 10.1016/j.colsurfa.2021.126160
Hua Jin , Jun Dong , Xiaoshu Qu

A novel direct Z-scheme magnetic organic polymer gel decorating Ag3PO4 (Ag3PO4/Fe3O4/MP) photocatalyst was facilely synthesized by an in-situ method. Fe3O4/MP nanoparticles were randomly distributed on the surface of Ag3PO4 without blocking the structure completely. The Ag3PO4/Fe3O4/MP composite demonstrated enhanced photocatalytic performance for degradation of pollutants such as tetracycline (TC) and 4-Chlorophenol (p-CP). In addition, the photocatalyst has good recyclability and could be easily separated from the solution with the help of magnetic field. Finally, results of the trapping experiments indicated that radical dotO2, holes, and Oradical dotH were the major reactive species and the enhanced activity originated from the excellent synergistic effect between Ag3PO4 and Fe3O4/MP nanoparticles, forming a direct Z-scheme photocatalytic system.



中文翻译:

磁性有机聚合物凝胶修饰Ag 3 PO 4作为水净化的Z型光催化剂

通过原位合成方法,简便地合成了一种新型的Z型磁性有机高分子凝胶修饰的Ag 3 PO 4(Ag 3 PO 4 / Fe 3 O 4 / MP)光催化剂。Fe 3 O 4 / MP纳米颗粒随机分布在Ag 3 PO 4的表面上,而没有完全封闭结构。Ag 3 PO 4 / Fe 3 O 4/ MP复合材料对四环素(TC)和4-氯苯酚(p-CP)等污染物的降解具有增强的光催化性能。另外,光催化剂具有良好的可回收性,并且可以在磁场的帮助下容易地与溶液分离。最后,捕获实验的结果表明,激进点直径:2 - ,孔,和O 激进点H,分别为主要活性物质和增强的活性源于优异的协同效果的Ag之间3 PO 4和Fe 3 ö 4 / MP纳米颗粒,从而形成直接Z方案光催化系统。

更新日期:2021-01-25
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