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Helically chiral Pd(II) complexes containing intramolecular Pd⋯Pd metallophilicity as circularly polarized molecular phosphors
Chemical Communications ( IF 4.9 ) Pub Date : 2021-1-11 , DOI: 10.1039/d0cc08188d Jinqiang Lin 1, 2, 3, 4, 5 , Mo Xie 4, 5, 6, 7, 8 , Xiaobao Zhang 4, 5, 6, 7 , Qin Gao 4, 5, 6, 7 , Xiaoyong Chang 4, 5, 6, 7 , Chao Zou 4, 5, 6, 7 , Wei Lu 4, 5, 6, 7
Chemical Communications ( IF 4.9 ) Pub Date : 2021-1-11 , DOI: 10.1039/d0cc08188d Jinqiang Lin 1, 2, 3, 4, 5 , Mo Xie 4, 5, 6, 7, 8 , Xiaobao Zhang 4, 5, 6, 7 , Qin Gao 4, 5, 6, 7 , Xiaoyong Chang 4, 5, 6, 7 , Chao Zou 4, 5, 6, 7 , Wei Lu 4, 5, 6, 7
Affiliation
Carbon-centred chirality of the pincer-type cyclometalated ligands is transferred to the helical chirality of dinuclear and tetranuclear Pd(II) arylacetylide complexes, and hence phosphorescence with quantum yields up to 50% and dissymmetry factors in the 10−3 scale from the metal–metal-to-ligand charge-transfer excited states has been recorded in diluted solutions.
中文翻译:
分子内具有Pd⋯Pd嗜金属性的螺旋手性Pd(II)配合物,为圆极化分子磷
钳型环金属化配体的以碳为中心的手性转移到双核和四核Pd(II)芳基乙炔配合物的螺旋手性,因此磷光的量子产率高达50%,且金属的不对称因子为10 -3 –在稀释溶液中记录了金属到配体的电荷转移激发态。
更新日期:2021-01-18
中文翻译:
分子内具有Pd⋯Pd嗜金属性的螺旋手性Pd(II)配合物,为圆极化分子磷
钳型环金属化配体的以碳为中心的手性转移到双核和四核Pd(II)芳基乙炔配合物的螺旋手性,因此磷光的量子产率高达50%,且金属的不对称因子为10 -3 –在稀释溶液中记录了金属到配体的电荷转移激发态。