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Ferrocene containing redox-responsive poly(2-oxazoline)s
Chemical Communications ( IF 4.9 ) Pub Date : 2020-12-23 , DOI: 10.1039/d0cc07830a
Philipp S. Borchers 1, 2, 3, 4, 5 , Michael Dirauf 1, 2, 3, 4, 6 , Maria Strumpf 1, 2, 3, 4, 5 , Helmar Görls 3, 4, 7, 8, 9 , Christine Weber 1, 2, 3, 4, 6 , Martin D. Hager 1, 2, 3, 4, 5 , Ulrich S. Schubert 1, 2, 3, 4, 5
Affiliation  

A new monomer, 2-ferrocene-ethyl-2-oxazoline, was copolymerized with 2-alkyl-2-oxazolines. The cationic ring opening polymerization (CROP) of 2-oxazolines allows the synthesis of well-defined copolymers with adjustable molar masses as well as end-group control, which was also evident from kinetic studies. The utilization of this new comonomer led to redox-active polymers as proven by UV-VIS-measurements and cyclic-voltammetry.

中文翻译:

含二茂铁的氧化还原响应性聚(2-恶唑啉)

将新的单体2-二茂铁-乙基-2-恶唑啉与2-烷基-2-恶唑啉共聚。2-恶唑啉的阳离子开环聚合反应(CROP)可以合成具有可调节摩尔质量以及端基控制的定义明确的共聚物,这从动力学研究中也很明显。这种新的共聚单体的使用导致了氧化还原活性聚合物,这已通过UV-VIS测量和循环伏安法证明。
更新日期:2021-01-18
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