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Synthesis and characterization of poly-3-(9H-carbazol-9-yl)propylmethacrylate as a gel electrolyte for dye-sensitized solar cell applications
Polymer Bulletin ( IF 3.2 ) Pub Date : 2021-01-18 , DOI: 10.1007/s00289-021-03541-z
Ummu Habeeba Abdul Azeez , Ahalya Gunasekaran , Andrea Sorrentino , Asad Syed , Najat Marraiki , Sambandam Anandan

Poly-3-(9H-carbazol-9-yl)propylmethacrylate (pCMA) is synthesized as a polymer gel electrolyte and employed in the fabrication of dye-sensitized solar cells (DSSC). The pCMA was characterized by various analytical techniques to examine its structural and thermal properties. The photovoltaic and electrochemical effects of this electrolyte in DSSCs were investigated. From the results, it was found that DSSCs assembled with pCMA-PGE is an efficient electrolyte, which yields an open-circuit voltage 545 mV and current density 10 mA for a cell of area 0.25 cm2. pCMA-PGE device shows better performance (η = 2.2%), and it also performs as a good host polymer matrix for redox couple in the electrolyte.

中文翻译:

聚-3-(9H-咔唑-9-基)丙基甲基丙烯酸酯的合成和表征作为染料敏化太阳能电池应用的凝胶电解质

聚-3-(9H-咔唑-9-基)丙基甲基丙烯酸酯 (pCMA) 被合成为聚合物凝胶电解质,并用于制造染料敏化太阳能电池 (DSSC)。pCMA 通过各种分析技术进行表征,以检查其结构和热性能。研究了这种电解质在 DSSC 中的光伏和电化学效应。结果表明,与 pCMA-PGE 组装的 DSSCs 是一种高效的电解质,对于面积为 0.25 cm2 的电池产生 545 mV 的开路电压和 10 mA 的电流密度。pCMA-PGE 器件表现出更好的性能(η = 2.2%),并且它还是电解质中氧化还原对的良好主体聚合物基质。
更新日期:2021-01-18
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