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Synthesis and electrorheological properties of silica-coated MoS2 nanocomposites with hierarchical and core-shell structure
Journal of the Taiwan Institute of Chemical Engineers ( IF 5.7 ) Pub Date : 2021-01-15 , DOI: 10.1016/j.jtice.2021.01.009
Weijian Sun , Zhenyu Xi , Haonan Zheng , Yi Chen , Changhao Li , Baoxiang Wang , Chuncheng Hao

The silicon oxide coated flower-like sheet layered MOS2 is synthesized by a simple two-step method, in which a modified hydrothermal method was firstly used to synthesize 3D radically oriented MoS2 nanoflowers initially and increase the surface area and enhance the active site to enable the SiO2 to grow on MoS2 uniformly by using a modified hydrolysis method. Field emission scanning electron microscope (SEM), energy-dispersive spectrometer (EDS), transmission electron microscope (TEM), X-ray powder diffractometer (XRD), Fourier infrared spectrometer (FI-IR), X-ray photoelectron spectroscopy (XPS) etc., were used to characterize the morphology, structure, and chemical composition state of the monodispersed and characterized core/shell nanoparticles. At the same time, a high-voltage vol rotary rheometer was used to test the ER performance and dielectric performance of the prepared MoS2/SiO2-based suspension. The comprehensive analysis of rheological, dielectric, and conductive properties shows that MoS2/SiO2-based electrorheological fluid is a very promising electrorheological fluid material.



中文翻译:

具有分级和核-壳结构的二氧化硅包覆的MoS 2纳米复合材料的合成和电流变特性

通过简单的两步法合成了氧化硅涂层的花状片状层状MOS 2,该方法首先使用改进的水热法合成3D自由基取向的MoS 2纳米花,并增加表面积并增强活性位点。使SiO 2在MoS 2上生长通过使用改良的水解方法均匀地进行。场发射扫描电子显微镜(SEM),能量色散光谱仪(EDS),透射电子显微镜(TEM),X射线粉末衍射仪(XRD),傅立叶红外光谱仪(FI-IR),X射线光电子能谱(XPS)等用于表征单分散和表征的核/壳纳米粒子的形态,结构和化学组成状态。同时,使用高压vol旋转流变仪测试制备的基于MoS 2 / SiO 2的悬浮液的ER性能和介电性能。流变,介电和导电性能的综合分析表明,MoS 2 / SiO 2基的电流变流体是非常有前途的电流变流体材料。

更新日期:2021-02-05
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