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Coupling the Individual Motions of the Machine-like Components of Zirconium(IV) Organic Frameworks
Chem ( IF 23.5 ) Pub Date : 2021-01-14 , DOI: 10.1016/j.chempr.2020.12.014
Adrian Saura-Sanmartin , Alberto Martinez-Cuezva , Jose Berna

Controlling the internal molecular dynamics in reticular materials is a major challenge for the development of nanotechnological applications. In this issue of Chem, Schurko, Loeb, and co-workers show how the ring motion of the [2]rotaxane-based linker and that of the surrounding triphenylene-based struts influence each other within a series of robust zirconium(IV) organic frameworks.



中文翻译:

耦合锆(IV)有机骨架的机械成分的各个运动

网状材料中内部分子动力学的控制是纳米技术应用发展的主要挑战。在本期《化学》杂志中,Schurko,Loeb及其同事展示了[2]轮烷烷烃基连接基团和周围的三亚苯基支杆的环向运动在一系列坚固的锆(IV)有机物中如何相互影响。构架。

更新日期:2021-01-14
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