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Does Von Neumann Entropy Correspond to Thermodynamic Entropy?
Philosophy of Science ( IF 1.7 ) Pub Date : 2021-01-01 , DOI: 10.1086/710072
Eugene Y. S. Chua

Conventional wisdom holds that the von Neumann entropy corresponds to thermodynamic entropy, but Hemmo and Shenker (2006) have recently argued against this view by attacking von Neumann's (1955) argument. I argue that Hemmo and Shenker's arguments fail due to several misunderstandings: about statistical mechanical and thermodynamic domains of applicability, about the nature of mixed states, and about the role of approximations in physics. As a result, their arguments fail in all cases: in the single-particle case, the finite particles case, and the infinite particles case.

中文翻译:

冯诺依曼熵对应于热力学熵吗?

传统观点认为冯诺依曼熵对应于热力学熵,但 Hemmo 和 Shenker (2006) 最近通过攻击冯诺依曼 (1955) 的论点来反对这一观点。我认为 Hemmo 和 Shenker 的论点因以下几个误解而失败:关于适用性的统计力学和热力学领域,关于混合态的性质,以及关于近似值在物理学中的作用。结果,他们的论点在所有情况下都失败了:在单粒子情况下、有限粒子情况下和无限粒子情况下。
更新日期:2021-01-01
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