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Sulfur- and nitrogen-doped rice husk-derived C/SiOx composites as high-performance lithium-ion battery anodes
Solid State Ionics ( IF 3.2 ) Pub Date : 2021-01-13 , DOI: 10.1016/j.ssi.2021.115548
Jinlong Cui , Yang Qiu , Haibang Zhang , Zhendong Yao , Wenyuan Zhao , Yunying Liu , Juncai Sun

To enhance the comprehensive utilization of agricultural waste in new energy materials, sulfur/nitrogen dual-doped porous C/SiOx composites (SN@C/SiOx) are successfully prepared via a facile and economical method. In this approach, rice husks are used as the C and Si source and thiourea as the S and N source. This SN@C/SiOx composite possesses a high specific surface area and SiOx particles are evenly distributed in the S/N-doped C matrix. The S/N-doped C matrix not only improves electrical conductivity and impedes the agglutination of particles, but also buffers the volume variation of SiOx, achieving enhanced electrochemical properties. As a lithium-ion battery (LIBs) anode, the as-synthesized SN@C/SiOx composite delivers an impressive specific capacity (1150 mAh/g) and enhanced initial coulombic efficiency (CE) of 70.4%. Even at a large current density of 1.0 A/g, the reversible capacity remains 632 mAh/g after 1200 cycles. This doping carbonization strategy offers the potential for using rice husks in the development of high-performance lithium ion batteries.



中文翻译:

硫和氮掺杂的稻壳衍生的C / SiO x复合材料作为高性能锂离子电池阳极

为提高农业废弃物在新能源材料中的综合利用,通过简便,经济的方法成功制备了硫/氮双掺杂多孔C / SiO x复合材料(SN @ C / SiO x)。在这种方法中,稻壳用作C和Si来源,硫脲用作S和N来源。这种SN @ C / SiO x复合材料具有较高的比表面积,并且SiO x颗粒均匀分布在S / N掺杂的C基体中。掺S / N的C基体不仅提高了电导率并阻止了颗粒的凝集,而且还缓冲了SiO x的体积变化,从而实现了增强的电化学性能。作为锂离子电池(LIB)阳极,合成后的SN @ C / SiOx复合材料具有令人印象深刻的比容量(1150 mAh / g),初始库仑效率(CE)提高了70.4%。即使在1.0 A / g的大电流密度下,在1200次循环后,可逆容量仍保持632 mAh / g。这种掺杂碳化策略为开发高性能锂离子电池提供了使用稻壳的潜力。

更新日期:2021-01-13
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