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Synthesis and Characterization of the Energetic 3‐Azido‐5‐amino‐6‐nitro‐1,2,4‐triazine
Propellants, Explosives, Pyrotechnics ( IF 1.8 ) Pub Date : 2021-01-12 , DOI: 10.1002/prep.202000136
Shannon E. Creegan 1 , Matthias Zeller 2 , Edward F. C. Byrd 3 , Davin G. Piercey 1
Affiliation  

The reaction of diazotetrazole with nitroacetonitrile led to the isolation of the simple 1,2,4‐triazine‐based energetic 3‐azido‐5‐amino‐6‐nitro‐1,2,4‐triazine. It and related compounds were chemically characterized by NMR, IR, and single‐crystal X‐ray crystallography. Their energetic sensitivities (impact, friction) were experimentally determined and energetic performances calculated. The ability of 3‐azido‐5‐amino‐6‐nitro‐1,2,4‐triazine to form N‐oxides was also studied.

中文翻译:

含氮3-叠氮基-5-氨基-6-硝基1,2,4-三嗪的合成与表征

重氮四唑与硝基乙腈的反应导致分离出简单的基于1,2,4-三嗪的高能3-叠氮基-5-氨基-6-硝基1,2,4-三嗪。它和相关化合物通过NMR,IR和单晶X射线晶体学进行了化学表征。通过实验确定它们的能量敏感性(冲击,摩擦)并计算能量性能。还研究了3-叠氮基-5-氨基-6-硝基1,2,4-三嗪形成N-氧化物的能力。
更新日期:2021-02-03
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