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Selective dimerization of cyclohexene over a Re2O7-B2O3/Al2O3 catalyst under mild conditions
Molecular Catalysis ( IF 4.6 ) Pub Date : 2021-01-11 , DOI: 10.1016/j.mcat.2021.111398 Alexander A. Greish , Alexandra P. Barkova , Elena D. Finashina , Tapio O. Salmi , Leonid M. Kustov
中文翻译：
在温和条件下在Re 2 O 7 -B 2 O 3 / Al 2 O 3催化剂上环己烯的选择性二聚
更新日期：2021-01-11
Molecular Catalysis ( IF 4.6 ) Pub Date : 2021-01-11 , DOI: 10.1016/j.mcat.2021.111398 Alexander A. Greish , Alexandra P. Barkova , Elena D. Finashina , Tapio O. Salmi , Leonid M. Kustov
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A Re2O7-B2O3/Al2O3 catalyst was demonstrated to reveal significant activity in cyclohexene dimerization into 1-cyclohexenylcyclohexane with a total yield of 95 % and a selectivity close to 100 % in the batch mode at 75−80°C and atmospheric pressure.
中文翻译：
在温和条件下在Re 2 O 7 -B 2 O 3 / Al 2 O 3催化剂上环己烯的选择性二聚
Re 2 O 7 -B 2 O 3 / Al 2 O 3催化剂显示出在环己烯二聚成1-环己烯基环己烷中的显着活性，在75-下的分批模式下总收率为95％，选择性接近100％。 80°C和大气压。
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