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Ultralow-detection limit ammonia gas sensors at room temperature based on MWCNT/WO3 nanocomposite and effect of humidity
Solid State Sciences ( IF 3.5 ) Pub Date : 2021-01-08 , DOI: 10.1016/j.solidstatesciences.2021.106534
Vu Truong Duong , Cong Tu Nguyen , Huu Bac Luong , Duc Chien Nguyen , Huu Lam Nguyen

Nanocomposite-based NH3 gas sensors working at room temperature were systematically fabricated by compositing multi-walled carbon nanotubes (MWCNTs) and tungsten oxide (WO3) nanobricks at different mass ratios. The response of the nanocomposite-based sensors increases with increasing WO3 content from 0 to 95 wt% then decreases as the WO3 content continuously increases to 100 wt%. The sensor with 95 wt% of WO3 shows a significant enhancement in NH3 gas sensing characteristics, namely, high response (~350% with 60 ppm NH3), ultralow limit of detection (6 ppb), and selectivity to NH3. The enhancement of gas sensing characteristics was attributed to the synergistic effect of the p-p junction between MWCNT and the inversion layer on the WO3 surface caused by the adsorbed oxygen gas and water vapor in ambient air. The response increases while the sensor's resistance decreases with increasing relative humidity from 25% to 65%. Hence, MWCNT/WO3 nanocomposite is a promising material for selective sub-ppm NH3 gas sensor at room temperature.



中文翻译:

基于MWCNT / WO3纳米复合材料的室温超低检测极限氨气传感器及湿度影响

通过复合不同质量比的多壁碳纳米管(MWCNT)和氧化钨(WO 3)纳米砖,系统地制造了在室温下工作的基于纳米复合材料的NH 3气体传感器。纳米复合材料传感器的响应随着WO 3含量从0到95 wt%的增加而增加,然后随着WO 3含量连续增加到100 wt%而降低。含有95 wt%WO 3的传感器在NH 3气敏特性方面表现出显着增强,即高响应(在60 ppm NH 3时约为350%),超低检测限(6 ppb)和对NH 3的选择性。气体感测特性的增强归因于周围空气中吸附的氧气和水蒸气引起的MWCNT与WO 3表面上的反型层之间pp结的协同效应。当相对湿度从25%增加到65%时,响应增加,而传感器的电阻减小。因此,MWCNT / WO 3纳米复合材料是用于室温下选择性亚ppm NH 3气体传感器的有前途的材料。

更新日期:2021-01-18
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