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Enhanced Stokes-shift and dispersibility in non-polar PMMA solvent of CdTe quantum dots by silica coating
Chemical Physics ( IF 2.3 ) Pub Date : 2021-01-09 , DOI: 10.1016/j.chemphys.2021.111102
Alvaro Flores-Pacheco , Raúl Sánchez-Zeferino , Gerardo Saavedra-Rodríguez , Jorge Indalecio Contreras-Rascón , Joel Díaz-Reyes , Mario Enrique Álvarez-Ramos

Silica-coated cadmium telluride quantum dots (CdTe@SiO2) exhibit increased sensitivity to UV illumination within the 300–400 nm range, allowing long and efficient Stokes-shifted emissions with more than 300 nm of separation from the excitation source. In addition, the surface modification of water-soluble CdTe quantum dots promotes a better dispersibility in a non-polar solvent (chloroform), allowing the facile fabrication of a highly luminescent PMMA/CdTe@SiO2 composite with uniformly distributed CdTe@SiO2 clusters suitable for photonic applications.



中文翻译:

二氧化硅涂层增强了CdTe量子点在非极性PMMA溶剂中的斯托克斯位移和分散性

涂有二氧化硅的碲化镉量子点(CdTe @ SiO 2)对300-400 nm范围内的紫外线照射具有更高的灵敏度,允许长且有效的斯托克斯位移发射,与激发源的分离距离超过300 nm。此外,水溶性CdTe量子点的表面改性促进了其在非极性溶剂(氯仿)中的更好分散性,从而可以轻松制造具有均匀分布CdTe @ SiO 2簇的高发光PMMA / CdTe @ SiO 2复合材料适用于光子应用。

更新日期:2021-01-24
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