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Comparative study of zeolites matrices in bio-wastes pyrolytic valorization
Process Safety and Environmental Protection ( IF 7.8 ) Pub Date : 2021-01-07 , DOI: 10.1016/j.psep.2021.01.013
Carla S. Fermanelli , Liliana B. Pierella , Clara Saux

Considering the importance of bio-wastes thermo-chemical conversion to fuel and platform molecules, three types of zeolites (ZSM-5, Beta and Y) were tested as heterogeneous catalysts. Peanut shell is a high volume agricultural waste. Its pyrolysis mediated by different catalysts was evaluated. The effect of the zeolite matrix over the bio-oil yield and products selectivities was carefully considered. Fresh and used materials were widely characterized by XRD, FTIR, ICP and BET techniques. Pyrolysis reactions were done at 500 °C under N2 flow. The use of zeolites in biomass pyrolysis showed interesting results in terms of bio-oil composition. When H-ZSM-5 catalyst was employed, higher bio-oil yields and greater concentration of aromatic hydrocarbons and furans were obtained.



中文翻译:

生物废物热解增值中沸石基质的比较研究

考虑到生物废物热化学转化为燃料和平台分子的重要性,测试了三种沸石(ZSM-5,Beta和Y)作为多相催化剂。花生壳是一种大量的农业废弃物。评价了其在不同催化剂作用下的热解。仔细考虑了沸石基质对生物油收率和产物选择性的影响。XRD,FTIR,ICP和BET技术对新鲜和用过的材料进行了广泛表征。在N 2流下于500°C进行热解反应。在生物油热解中使用沸石显示出有趣的结果,涉及生物油的组成。当使用H-ZSM-5催化剂时,获得了更高的生物油产率以及更高浓度的芳族烃和呋喃。

更新日期:2021-01-07
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