The review contains an analysis of the literature data in the field of mechanisms of catalytic organic reactions, including an Ag⁺ ion or a silver nanoparticle and a compound containing triple CC and NC bonds. For organic compounds containing an alkyne cc moiety, the intermediate states for both types of catalysts are similar. In the case of isonitriles, only Ag⁺ compounds have a catalytic effect. Apparently, the stability constants of isonitrile π-complexes with the participation of formal zero-valent silver do not allow the transformation of organic compounds to be carried out at the required rate.

中文翻译：

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银离子和纳米粒子催化炔烃和异腈转化机理的异同

该综述对催化有机反应机理领域的文献数据进行了分析，包括Ag ⁺离子或银纳米颗粒以及含有三键C C和N C键的化合物。对于含有炔烃cc部分的有机化合物，两种类型催化剂的中间状态均相似。对于异腈，只有Ag ⁺化合物具有催化作用。显然，在具有正式的零价银的情况下，异腈π络合物的稳定常数不允许以所需的速率进行有机化合物的转化。