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Preparation of a tantalum-based MoSi2–Mo coating resistant to ultra-high-temperature thermal shock by a new two-step process
Journal of Materials Science & Technology ( IF 10.9 ) Pub Date : 2021-01-07 , DOI: 10.1016/j.jmst.2020.11.059
Sainan Liu , Hongtai Shen , Jiawei Xu , Xiaojun Zhou , Jianfei Liu , Zhenyang Cai , Xiaojun Zhao , Lairong Xiao

To develop an ultra-high-temperature resistant coating for a reusable thermal protection system, the preparation of a tantalum-based MoSi2-Mo coating by a new two-step process of multi-arc ion plating and halide activated pack cementation is presented. The coating has a dense structure and is well compatible with the tantalum substrate, which can be thermally shocked from room temperature to 1750 °C for 360 cycles without failure. The mechanism of the coating’s excellent resistance to high-temperature thermal shocks is that a strong-binding gradient interface and a dense SiO2 oxide scale with good oxygen resistance are formed by the high-temperature self-diffusion of Si.



中文翻译:

通过新的两步法制备抗超高温热冲击的钽基MoSi 2 -Mo涂层

为了开发用于可重复使用的热保护系统的耐超高温涂层,提出了通过多弧离子镀和卤化物活化包胶结的新两步工艺制备钽基MoSi 2 -Mo涂层。该涂层具有致密的结构,并且与钽基板具有良好的相容性,可以将其从室温热震至1750°C,持续360个循环,而不会发生故障。涂层对高温热冲击具有出色的抵抗性的机理是,Si的高温自扩散形成了牢固的结合梯度界面和致密的SiO 2氧化皮,并具有良好的耐氧性。

更新日期:2021-01-07
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