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Plasmon-Driven Photothermal Conversion with Two-Dimensional Ultra-thin PdFe Nanosheets for Ethylene Glycol Electrooxidation
Plasmonics ( IF 3 ) Pub Date : 2021-01-06 , DOI: 10.1007/s11468-020-01342-0
Di Zhang , Chaoyang Zhang , Hongxu Gao , Jing Sui , Ning Sui , Lina Wang , Manhong Liu , William W. Yu

Pd-based nanostructures have high catalytic activity and good light trapping ability for photothermal catalysis. In this work, PdFe nanosheets (NSs) were synthesized through a hydrothermal method and efficiently catalyzed ethylene glycol electrooxidation reaction (EGOR). Under the irradiation of light, the mass activity of EGOR enhanced 1.78 times (from 4.02 to 7.17 A mg−1) comparing with no light, which was 18 times higher than commercial Pd/C. The high activity is attributed to the combination of high photothermal conversion efficiency and the exposure of high energy facet (111) of PdFe NSs. The effects of Pd/Fe ratio, light intensity, and wavelength were investigated.



中文翻译:

二维超薄PdFe纳米片的等离子驱动光热转化用于乙二醇电氧化

钯基纳米结构具有较高的催化活性和良好的光热催化捕光能力。在这项工作中,通过水热法合成了PdFe纳米片(NSs),并有效地催化了乙二醇电氧化反应(EGOR)。在没有光的情况下,EGOR的质量活性提高了1.78倍(从4.02至7.17 A mg -1),比无光Pd / C高18倍。高活性归因于高光热转换效率和PdFe NSs高能面(111)的暴露。研究了钯/铁比,光强度和波长的影响。

更新日期:2021-01-06
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