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Morphology controlled synthesis of one-dimensional CoMn 2 O 4 nanorods for high-performance supercapacitor electrode application
Chemical Papers ( IF 2.2 ) Pub Date : 2021-01-05 , DOI: 10.1007/s11696-020-01448-z
T. Antony Sandosh , A. Simi

Facile preparation of one-dimensional spinel material is highly attractive for their widespread usage in energy storage devices. Herein, we report uniform one-dimensional CoMn2O4 nanorods were prepared by cetyl trimethyl ammonium bromide (CTAB) assisted hydrothermal technique followed by subsequent calcination process. The prepared materials were characterized to different types of physicochemical features to analyze the appropriateness of the material for the supercapacitor electrode application. The crystalline nature and bonding properties were examined by X-ray diffraction analysis and Fourier-transform infrared spectroscopic analysis. The structural and morphological features of prepared materials were analyzed using field emission scanning electron microcopy which reveals the edge curved one-dimensional nanorod structure. Furthermore, cyclic voltammetric, chronopotentiometric and electrochemical impedance spectroscopic analyses were employed to evaluate the electrochemical properties of the freshly prepared CoMn2O4 materials. The cyclicvoltammetric studies provide the specific capacitance of 895 Fg−1 at a scan rate of 5 mV s−1, whereas chronopotentiometric curves provide the highest specific capacitance of 802 Fg−1 at current density of 1 Ag−1. The cyclic stability analysis shows the excellent cyclic stability which retains 87% of initial capacitance after the continuous 5000 CV cycles at a scan rate of 100 mVs−1. The outstanding electrochemical features unquestionably make CoMn2O4 as a good candidate for supercapacitor devices.



中文翻译:

用于高性能超级电容器电极应用的一维CoMn 2 O 4纳米棒的形貌控制合成

一维尖晶石材料的简便制备因其在能量存储设备中的广泛使用而极具吸引力。在此,我们报告均匀的一维CoMn 2 O 4十六烷基三甲基溴化铵(CTAB)辅助水热技术制备纳米棒,随后进行煅烧。将所制备的材料表征为不同类型的物理化学特征,以分析该材料对于超级电容器电极应用的适用性。通过X射线衍射分析和傅里叶变换红外光谱分析检查了晶体性质和键合性质。使用场发射扫描电子显微镜分析了所制备材料的结构和形态特征,揭示了边缘弯曲的一维纳米棒结构。此外,采用循环伏安法,计时电位法和电化学阻抗谱分析法评估了刚制备的CoMn的电化学性能。2 O 4材料。循环伏安研究在5 mV s -1的扫描速率下提供了895 Fg -1的比电容,而计时电位曲线在1 Ag -1的电流密度下提供了802 Fg -1的最高比电容。循环稳定性分析显示了出色的循环稳定性,在以100 mVs -1的扫描速率连续进行5000 CV循环后,它保留了初始电容的87%。出色的电化学特性无疑使CoMn 2 O 4成为超级电容器器件的良好候选者。

更新日期:2021-01-05
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