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Armoring Black Phosphorus Anode with Stable Metal–Organic-Framework Layer for Hybrid K-Ion Capacitors
Nano-Micro Letters ( IF 26.6 ) Pub Date : 2021-01-04 , DOI: 10.1007/s40820-020-00570-7
Mengzhu Xu 1, 2 , Yutong Feng 1, 2 , Bingjie Chen 2 , Ruijin Meng 2 , Mengting Xia 2 , Feng Gu 3 , Donglei Yang 4 , Chi Zhang 1, 2 , Jinhu Yang 1, 2
Affiliation  

  • The ultrathin metal–organic-framework (MOF) interphase layer with high mechanical/chemical stability was in situ grown on black phosphorus nanosheets (BPNSs).

  • MOF interphase layers as an ordered porous and robust protective layer can facilitate K ion diffusion and accommodate the volume change of the electrode.

  • Benefiting from the improved reaction kinetics and enhanced electrode stability, the BPNS@MOF anode for potassium-ion capacitors exhibits outstanding cycle performance.



中文翻译:

用于混合 K 离子电容器的具有稳定金属有机框架层的铠装黑磷阳极

  • 具有高机械/化学稳定性的超薄金属-有机框架(MOF)界面层在黑磷纳米片(BPNS)上原位生长。

  • MOF 界面层作为有序的多孔和坚固的保护层可以促进 K 离子扩散并适应电极的体积变化。

  • 受益于改进的反应动力学和增强的电极稳定性,用于钾离子电容器的 BPNS@MOF 阳极表现出出色的循环性能。

更新日期:2021-01-04
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