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The Opportunities and Challenges for NH 3 Oxidation with 100% Conversion and Selectivity
Catalysis Surveys from Asia ( IF 3 ) Pub Date : 2021-01-03 , DOI: 10.1007/s10563-020-09320-6
Zhong Wang , Shuangju Li , Chuanhui Zhang , Da Wang , Xuebing Li

The selective catalytic oxidation of ammonia (SCO) to N2 seems to be the most promising technology to remove NH3. Compared with electrocatalytic and photocatalytic ammonia oxidation technology, the thermal catalytic oxidation ammonia technology was sufficient to support large-scale commercial and industrial applications. The NH3-SCO reaction was strongly obeyed the reaction routes of imide, hydrazinium-type and iSCR mechanism. Further, in situ (electron paramagnetic resonance) EPR spectroscopy combined with DFT calculation could provide a foundation for the design and construction of highly efficient ammonia oxidation catalyst. Finally, important ideas for NH3-SCO should be given the 100% N2 selectivity and higher NH3 conversion at lowest temperature. If Ag single-atoms were inserted in the tunnels of zeolites or MOF to result in single Ag atoms anchored at the tunnel, this single-atom Ag particles exhibited super NH3 conversion, N2 selectivity and hydrothermal durability at low temperatures.



中文翻译:

100%转化率和选择性的NH 3氧化的机遇与挑战

氨(SCO)选择性催化氧化为N 2似乎是去除NH 3的最有希望的技术。与电催化和光催化氨氧化技术相比,热催化氧化氨技术足以支持大规模的商业和工业应用。NH 3 -SCO反应强烈遵循酰亚胺,肼型和iSCR反应机理。此外,原位(电子顺磁共振)EPR光谱结合DFT计算可以为高效氨氧化催化剂的设计和建造提供基础。最后,对于NH 3 -SCO的重要构想应赋予100%N 2最低温度下具有较高的选择性和较高的NH 3转化率。如果将Ag单原子插入沸石或MOF的隧道中以导致单个Ag原子锚定在隧道中,则该单原子Ag颗粒在低温下表现出超高的NH 3转化率,N 2选择性和水热耐久性。

更新日期:2021-01-03
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