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Electrospun Co 3 O 4 nanoparticles and its methanol detection property
Applied Nanoscience ( IF 3.869 ) Pub Date : 2021-01-03 , DOI: 10.1007/s13204-020-01623-4
Kampara Roopa Kishore , Leela Bharani Teddu , Deenadhayalan Balamurugan , Jeyaprakash Beri Gopalakrishnan

PVA/Co3O4 beads-free nanofibers were prepared with PVA (polyvinyl alcohol) and cobalt(II) chloride hexahydrate (CoCl2⋅6H2O) as precursor solution by the electrospinning method. Structural studies of Co3O4 nanoparticles were analyzed with X-ray diffraction (XRD) studies and proved crystalline. Morphological studies were performed with a field emission scanning electron microscope (FESEM) characterization, which revealed that electrospun nanofibers were smoothly edged and randomly distributed along the substrate. The PVA/Co3O4 nanofibers were calcined to obtain nanoparticles in the one-dimension-like arrangement. Vapour sensing studies of Co3O4 nanoparticles were performed towards the detection of the pulmonary disease biomarkers. The sensing characteristics were analyzed at various temperatures ranging from room temperature to 350 °C and it was observed that Co3O4 nanoparticles showed a better response to methanol at 350 °C. At the operating temperature of 350 °C, Co3O4 nanoparticle sensing studies were performed towards 21–2094 ppm of methanol. Co3O4 nanoparticles showed good sensing characteristics with quick response and recovery time towards methanol vapour, which helps in the detection of pulmonary disease through an exhaled breath.



中文翻译:

电纺Co 3 O 4纳米粒子及其甲醇检测性能

PVA / Co的3 ö 4名用PVA(聚乙烯醇)和钴制备珠-自由纳米纤维(II)六水合物(氯化钴2 ⋅6H 2 O),通过静电纺丝法的前体溶液。通过X射线衍射(XRD)研究分析了Co 3 O 4纳米颗粒的结构,并证明了其结晶性。用场发射扫描电子显微镜(FESEM)表征进行了形态学研究,结果表明电纺纳米纤维边缘光滑且沿基材随机分布。PVA / Co 3 O 4将纳米纤维煅烧以获得一维状排列的纳米颗粒。进行了Co 3 O 4纳米颗粒的蒸气感测研究,以检测肺部疾病的生物标志物。在从室温到350°C的各种温度下分析了感测特性,观察到Co 3 O 4纳米颗粒在350°C下对甲醇表现出更好的响应。在350°C的工作温度下,对甲醇21–2094 ppm进行了Co 3 O 4纳米颗粒感测研究。钴3 O 4 纳米颗粒显示出良好的传感特性,对甲醇蒸气的响应迅速,恢复时间短,有助于通过呼气来检测肺部疾病。

更新日期:2021-01-03
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