In this work, we fabricated first-ever nanohybrids ZnO nanowires (ZnO-NWs)/Metallic Nanotube Arrays (MeNTA) structure for the large-scale fabrication of highly dense laterally and vertical aligned ZnO-NWs. To prepare heterogeneous surface MeNTA by using sputter-deposition of different metallic glasses (Zr₅₅Cu₃₀Al₁₀Ni₅, Cu₄₇Zr₄₂Al₇Ti₄, Pd₇₂Cu₁₂Si₁₆, W₅₀Ni₂₅B₂₅ and Ni₅₄B_0.3Si₃₆Cr_2.7Fe₇) over on contact-hole arrays created by a photoresist template with 650 nm height and various diameter (2, 10 and 20 μm). A ZnO seed layer is deposited by sputtering method on MeNTA to provide the nucleation sites to grow the nanowires inside the MeNTA. To perform the material analysis like surface morphology, crystal structural, and optical properties were characterized by using scanning electron microscopy, X-ray diffraction, Raman, XPS and photoluminescence, respectively. Our results confirm that, the nanowires having the hexagonal wurtzite structure and presenting strong UV emissions can be used in optoelectronics, sensors, piezoelectric-nanogenerator, solar cells and battery applications.

在这项工作中，我们首次制造了纳米混合的ZnO纳米线（ZnO-NWs）/金属纳米管阵列（MeNTA）结构，用于大规模制造高密度的横向和垂直排列的ZnO-NWs。通过使用不同金属玻璃（Zr ₅₅ Cu ₃₀ Al ₁₀ Ni ₅，Cu ₄₇ Zr ₄₂ Al ₇ Ti ₄，Pd ₇₂ Cu ₁₂ Si ₁₆，W ₅₀ Ni ₂₅ B ₂₅和Ni ₅₄ B）的溅射沉积制备异质表面MeNTA _0.3 Si ₃₆铬_2.7Fe ₇）在由光刻胶模板产生的接触孔阵列上，该光刻胶模板具有650 nm的高度和各种直径（2、10和20μm）。通过溅射方法在MeNTA上沉积ZnO种子层，以提供成核位点，以在MeNTA内部生长纳米线。为了进行诸如表面形态，晶体结构和光学性质的材料分析，分别通过使用扫描电子显微镜，X射线衍射，拉曼，XPS和光致发光来表征。我们的结果证实，具有六方纤锌矿结构并呈现出强紫外线辐射的纳米线可用于光电，传感器，压电纳米发电机，太阳能电池和电池应用。