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Effect of Al on Corrosion Behavior of Imitation-Gold Cu-Zn-Ni-Sn Alloys in 3.5 wt.% NaCl solution
JOM ( IF 2.6 ) Pub Date : 2021-01-02 , DOI: 10.1007/s11837-020-04507-8
Xiangyu Yu , Zhu Xiao , Qian Yu , Zhou Li , Qian Lei , Jie Dai

The corrosion behavior of imitation-gold Cu-Zn-Ni-Sn alloys with and without Al was investigated by means of color difference testing, static corrosion measurements, scanning electron microscopy analysis, electrochemical impedance measurements, and x-ray photoelectron spectroscopy analysis. The results showed that aluminum inhibited dissolution of Zn and Sn by the formation of an oxide film on the surface of the Cu-Zn-Ni-Sn alloy during corrosion, effectively improving its corrosion resistance. A transition of the corrosion product from Cu2O and Cu(OH)2 to CuO occurred on the surface of Cu-Zn-Ni-Sn-Al alloy, and the corrosion rate of the alloy decreased with increasing corrosion time due to the formation of the oxidation film and the hydrophobic effect of Zn5(CO3)2(OH)6 in the product layer.



中文翻译:

Al对3.5 wt%NaCl溶液中仿金Cu-Zn-Ni-Sn合金腐蚀行为的影响

通过色差测试,静态腐蚀测量,扫描电子显微镜分析,电化学阻抗测量和X射线光电子能谱分析,研究了含铝和不含铝的仿金Cu-Zn-Ni-Sn合金的腐蚀行为。结果表明,铝在腐蚀过程中通过在Cu-Zn-Ni-Sn合金表面形成氧化膜来抑制Zn和Sn的溶解,有效地提高了其耐蚀性。Cu-Zn-Ni-Sn-Al合金表面发生了腐蚀产物从Cu 2 O和Cu(OH)2到CuO的转变,并且随着腐蚀时间的增加,合金的腐蚀速率降低。膜的氧化和Zn 5的疏水作用产物层中的(CO 32(OH)6

更新日期:2021-01-02
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