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Synthesis, characterization, and visible light–induced photocatalytic evaluation of WO3/NaNbO3 composites for the degradation of 2,4-D herbicide
Materials Today Chemistry ( IF 7.3 ) Pub Date : 2021-01-01 , DOI: 10.1016/j.mtchem.2020.100406
E.J. Hernández-Moreno , A. Martínez de la Cruz , L. Hinojosa-Reyes , J. Guzmán-Mar , M.A. Gracia-Pinilla , A. Hernández-Ramírez

In this research study, WO3/NaNbO3-coupled photocatalysts were synthesized at three WO3 mass ratios (15, 85, and 95 wt%) and characterized. These composites were characterized via X-ray powder diffraction, N2 physisorption, UV–Vis diffuse reflectance spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, transmission electron microscopy, and photoluminescence techniques. For comparison, bare WO3 and NaNbO3 were also synthesized and characterized. 2,4-Dichlorophenoxyacetic acid (2,4-D) was degraded under visible light to evaluate its photocatalytic performance. The WO3 (95 wt%)/NaNbO3 composite showed higher photocatalytic activity than pure WO3 and NaNbO3 and even than the 15 and 85 wt% coupled materials; thus, the combination with the highest ratio of WO3 with respect to NaNbO3 showed increased photocatalytic activity compared with the bare materials.



中文翻译:

WO 3 / NaNbO 3复合材料降解2,4-D除草剂的合成,表征和可见光诱导的光催化评价

在该研究中,以三种WO 3质量比(15、85和95 wt%)合成WO 3 / NaNbO 3偶联光催化剂并进行了表征。这些复合材料通过X射线粉末衍射,N 2物理吸附,UV-Vis漫反射光谱,扫描电子显微镜,X射线光电子光谱,拉曼光谱,透射电子显微镜和光致发光技术进行了表征。为了比较,还合成和表征了裸露的WO 3和NaNbO 3。2,4-二氯苯氧基乙酸(2,4-D)在可见光下降解,以评估其光催化性能。WO 3(95 wt%)/ NaNbO 3该复合材料比纯WO 3和NaNbO 3甚至比15和85 wt%的偶合材料显示更高的光催化活性。因此,与裸材料相比,WO 3相对于NaNbO 3的比例最高的组合显示出增加的光催化活性。

更新日期:2021-01-01
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