当前位置: X-MOL 学术Phys. B Condens. Matter › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Study of energy release in Fe2O3/Al nano-thermite with graphene as an additional fuel
Physica B: Condensed Matter ( IF 2.8 ) Pub Date : 2020-12-31 , DOI: 10.1016/j.physb.2020.412803
Priya Thakur , Vimal Sharma , Nagesh Thakur

In nano-thermites, due to improper contacts between the reactants in solid-state reaction, the complete energy release during redox-reaction is still challenging. Here, Fe2O3/Al nano-thermite is synthesized with different weight fraction of multi-layered graphene (MLG) nanoplatelets by physical mixing technique. X-ray diffraction reveals that the synthesis method does not change the phase of reactants. The morphology of nano-thermite is examined by scanning electron microscopy and transmission electron microscopy which reveals that MLG nanoplatelets are homogeneously dispersed in the samples. Structural stability of MLG nanoplatelets present in nano-thermite is observed by Raman spectroscopy. The nano-thermite reaction is analyzed by differential scanning calorimetry. The results show that an increase in MLG content in nano-thermite sample Al/Fe2O3, from 0 wt% to 12 wt% is responsible for increase in the corresponding exothermic enthalpy from 71 J/g to 1537 J/g. On the contrary, ignition temperature and activation energy of these samples get reduced with increasing MLG.



中文翻译:

以石墨烯为辅助燃料的Fe 2 O 3 / Al纳米热矿中能量释放的研究

在纳米级半导体中,由于固态反应中反应物之间的接触不当,在氧化还原反应过程中完全释放能量仍然具有挑战性。在这里,Fe 2 O 3通过物理混合技术合成了不同重量分数的多层石墨烯(MLG)纳米片状的/ Al纳米铝热剂。X射线衍射表明该合成方法不会改变反应物的相。通过扫描电子显微镜和透射电子显微镜检查了纳米铁矿的形态,揭示了MLG纳米片均匀地分散在样品中。通过拉曼光谱观察了存在于纳米热液中的MLG纳米片的结构稳定性。通过差示扫描量热法分析纳米铝热反应。结果表明,纳米铝热样品Al / Fe 2 O 3中MLG含量增加,从0wt%到12wt%,负责使相应的放热焓从71J / g增加到1537J / g。相反,这些样品的着火温度和活化能随MLG的增加而降低。

更新日期:2020-12-31
down
wechat
bug