当前位置: X-MOL 学术Mater. Res. Bull. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Tuning the redox potential of Ag@Ag2O/WO3 and Ag@Ag2S/WO3 photocatalysts toward diclofenac oxidation and nitrophenol reduction
Materials Research Bulletin ( IF 5.4 ) Pub Date : 2020-12-31 , DOI: 10.1016/j.materresbull.2020.111193
Eman Torad , Eman H. Ismail , Mohamed Mokhtar Mohamed , Mostafa M.H. Khalil

WO3 nanoplates modified with either Ag2O or Ag2S nano-architectures were synthesized by a deposition-hydrothermal route (180 °C for 5 h). They were characterized using X-ray powder diffraction, N2 sorptiometry, Transmission electron microscopy, UV–vis diffuse reflectance spectroscopy, Photoluminescence spectroscopy, and X-ray photoelectron spectroscopy. The photo-catalytic (λ > 420 nm, 160 W) degradation of Diclofenac (DCF; 60 mg/l), was achieved using H2O2 (1 × 10−4 M) with either [email protected]2O/WO3 (K = 32.0 × 10-3 min-1) or [email protected]2S/WO3 (K = 7.3 × 10-3 min-1) catalysts. In the case of DCF degradation using radical scavengers, radical dotO2 played a key role in the degradation process whilst radical dotOH and holes acted moderately minor roles. The possible DCF degradation paths and intermediates were assessed by LC–MS. Both [email protected]2O/WO3 and [email protected]2S/WO3 catalysts were used in the photo-reduction of 4-nitrophenol (4-NP; 1.8 × 10−4 M) to 4-aminophenol (4-AP) with rate constants equal 8.3 x 10−3 min-1 and 1.6 x 10−3 min−1, respectively.



中文翻译:

调节Ag @ Ag2O / WO3和Ag @ Ag2S / WO3光催化剂的氧化还原电位,以实现双氯芬酸氧化和硝基苯酚还原

通过沉积-水热途径(180°C 5 h)合成了用Ag 2 O或Ag 2 S纳米结构改性的WO 3纳米板。使用X射线粉末衍射,N 2吸收法,透射电子显微镜,UV-vis漫反射光谱,光致发光光谱和X射线光电子光谱对它们进行了表征。使用H 2 O 2(1×10 -4 M)和[受电子邮件保护] 2 O / WO中的一种,可实现双氯芬酸(DCF; 60 mg / l)的光催化降解(λ> 420 nm,160 W)。3(K = 32.0×10 -3 min -1)或[电子邮件保护]2 S / WO 3(K = 7.3×10 -3 min -1)催化剂。在使用自由基清除剂的DCF退化的情况下,激进点Ø 2 -起到了降解过程中起关键作用,而激进点OH和空穴担任适度次要的角色。LC-MS评估了可能的DCF降解途径和中间体。[电子邮件保护的] 2 O / WO 3和[电子邮件保护的] 2 S / WO 3催化剂都用于将4-硝基苯酚(4-NP; 1.8×10 -4 M)光还原为4-氨基苯酚(4 -AP),速率常数等于8.3 x 10 -3 min -1和1.6 x 10 -3 min -1

更新日期:2020-12-31
down
wechat
bug