In this work, a series of HK/MCFs-x sorbents consisting of metal organic framework (HKUST-1) and mesocellular foams (MCFs) were prepared using solvothermal method. The samples were characterized by various techniques including XRD, N₂ adsorption/desorption, TG, SEM, FT-IR, and water vapor adsorption, respectively. The CO₂ adsorption isotherms and adsorption kinetic curves at different temperatures were obtained. Results showed that the Langmuir-Freundlich model and pseudo-first-order equation could be used to describe the CO₂ adsorption isotherms and kinetic curves, thus proving the exothermic, multilayer, physical adsorption processes. The isosteric heats of adsorption of the pure HKUST-1 and HK/MCFs-1 were in the range of 19–26 KJ/mol. The mass-transfer coefficient increased along with the temperature. The adsorption activation energies of the pure HKUST-1 and HK/MCFs-1 were 4.150 and 4.203 KJ/mol, respectively. Compared with the pure HKUST-1, HK/MCFs-1 had a substantially equivalent amount of CO₂ adsorption capacity under the same conditions, while the water resistance was improved. The CO₂ mass-transfer rate was higher than the pure HKUST-1. Meanwhile, HK/MCFs-1 also showed better recyclability.

在这项工作中，采用溶剂热法制备了由金属有机骨架（HKUST-1）和中孔泡沫（MCFs）组成的一系列HK / MCFs-x吸附剂。通过各种技术对样品进行表征，分别包括XRD，N ₂吸附/解吸，TG，SEM，FT-IR和水蒸气吸附。获得了不同温度下的CO ₂吸附等温线和吸附动力学曲线。结果表明，Langmuir-Freundlich模型和伪一阶方程可用于描述CO ₂吸附等温线和动力学曲线，从而证明了放热的多层物理吸附过程。纯的HKUST-1和HK / MCFs-1的吸附等构热范围为19-26 KJ / mol。传质系数随温度增加而增加。纯的HKUST-1和HK / MCFs-1的吸附活化能分别为4.150和4.203 KJ / mol。与纯HKUST-1相比，HK / MCFs-1在相同条件下的CO ₂吸附量基本相等，而耐水性得到改善。CO _2的传质速率高于纯HKUST-1。同时，HK / MCFs-1也显示出更好的可回收性。