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Ionic Liquid Synthesis of (Et3S)[Ag4I5] – A Structure Containing Basket‐Like Silver‐Iodide Cages with Ag22+ Pairs
Zeitschrift für anorganische und allgemeine Chemie ( IF 1.4 ) Pub Date : 2020-12-28 , DOI: 10.1002/zaac.202000338 Per H. Svensson 1, 2 , Lars Kloo 1
Zeitschrift für anorganische und allgemeine Chemie ( IF 1.4 ) Pub Date : 2020-12-28 , DOI: 10.1002/zaac.202000338 Per H. Svensson 1, 2 , Lars Kloo 1
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The compound (Et3S)[Ag4I5], 1, is readily synthesized from room‐temperature, ionic‐liquid media and displays a complex network structure of Ag6I6 cages with Ag22+ pairs forming 1D‐chains linked into layers distinctly separate from the disordered sulphonium cations. The compound should be regarded as a large‐bandgap semiconductor, but its significant structural voids qualify the compound a candidate for optoelectronic applications through the inclusion of suitable guest molecules.
中文翻译:
(Et3S)[Ag4I5]的离子液体合成-包含类似于Ag22 +对的篮式碘化银笼的结构
化合物(Et 3 S)[Ag 4 I 5 ],1易于从室温,离子液体介质中合成,并显示出复杂的Ag 6 I 6笼形网络结构,其中Ag 2 2+对形成一维链。连接成与无序sulph阳离子截然不同的层。该化合物应被视为带隙大的半导体,但其明显的结构空洞可通过包含合适的客体分子使该化合物成为光电应用的候选者。
更新日期:2021-02-05
中文翻译:
(Et3S)[Ag4I5]的离子液体合成-包含类似于Ag22 +对的篮式碘化银笼的结构
化合物(Et 3 S)[Ag 4 I 5 ],1易于从室温,离子液体介质中合成,并显示出复杂的Ag 6 I 6笼形网络结构,其中Ag 2 2+对形成一维链。连接成与无序sulph阳离子截然不同的层。该化合物应被视为带隙大的半导体,但其明显的结构空洞可通过包含合适的客体分子使该化合物成为光电应用的候选者。