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Preparation of carbon nanofibers supported Bi2MoO6 nanosheets as counter electrode materials on Titanium mesh substrate for dye-sensitized solar cells
Solar Energy ( IF 6.7 ) Pub Date : 2020-12-27 , DOI: 10.1016/j.solener.2020.11.064
Zixiang Li , Wankun Qi , Lidong Li , Zeyuan Ma , Weidong Lai , Ling Li , Xiaoshi Jin , Yucang Zhang , Wenming Zhang

A new type of counter electrode material Bismuth molybdate/carbon nanofibers (Bi2MoO6/CNFs) composite is synthesized by electrospinning and simple hydrothermal method and further used in dye-sensitized solar cells (DSSCs) on Titanium (Ti) mesh substrate, which shows strong stability and sustainable utilization. The introduction of titanium mesh and high catalytic activity of Bi2MoO6/CNFs materials provide a low transmission resistance and a large number of active sites that benefit electron transfer and the reduction I3 to I. A series of electrochemical measurements reveal that the DSSCs device assembled with Bi2MoO6/CNFs Ti mesh CE exhibit an excellent power conversion efficiency (PCE) of 9.02% which is higher than that of benchmark Platinum (Pt) CE (7.47%) and pure CNFs CE (7.48%), showing an outstanding electrochemical performance. Interestingly, the CNFs CE exhibits similar PCE with Pt CE, which is mainly owing to the application of Ti mesh substrate. These results show that the Bi2MoO6/CNFs Ti mesh CE can be a promising low-cost-effective replaceable CE for DSSCs.



中文翻译:

碳纳米纤维负载的Bi 2 MoO 6纳米片作为染料敏化太阳能电池的钛网基底上的对电极材料的制备

通过静电纺丝和简单水热法合成了一种新型的对电极材料钼酸铋/碳纳米纤维(Bi 2 MoO 6 / CNFs)复合材料,并进一步用于钛(Ti)网状衬底上的染料敏化太阳能电池(DSSC)中。显示出强大的稳定性和可持续利用性。引入钛的啮合和Bi的高催化活性2的MoO 6 /碳纳米纤维材料提供低透过性和效益电子转移和还原予大量活性位点的3 -至I - 。一系列电化学测量表明,DSSCs设备与Bi 2 MoO 6组装在一起/ CNFs Ti网状CE表现出9.02%的出色功率转换效率(PCE),高于基准铂(Pt)CE(7.47%)和纯CNFs CE(7.48%)的电能转换效率,显示出出色的电化学性能。有趣的是,CNFs CE与Pt CE表现出相似的PCE,这主要是由于Ti网状基板的应用。这些结果表明,Bi 2 MoO 6 / CNFs Ti网状CE可以成为一种有前途的低成本DSSC替代CE。

更新日期:2020-12-27
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