Metal–organic framework (MOF) and their derivatives have been considered a promising material in the field of energy storage and conversion systems. Their distinct properties, including high porosity, tunable composition, and structure, enable the design of materials with tailored properties for achieving high performance. Lithiumsulfur (LiS) batteries have several issues that prevent their broad application, including the low conductivity of sulfur, presence of soluble intermediates, and slow redox kinetics. MOF‐based materials are a synthetic platform that is well positioned to mitigate these issues. This review highlights three essential function of LiS batteries and classifies recently developed MOF‐based materials with respect to these functions. The design principles identified by such function‐based classification provide guidance and perspective to rationally design MOF‐based materials for advanced LiS batteries.

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用于高级锂的金属有机框架基材料的合理设计？S电池

金属有机框架（MOF）及其衍生物在能量存储和转换系统领域中被认为是很有前途的材料。它们具有独特的特性，包括高孔隙率，可调的组成和结构，可设计具有定制特性的材料以实现高性能。锂硫（李 S）电池具有防止其广泛应用的几个问题，包括硫的低导电性，可溶性中间体的存在，和缓慢的氧化还原动力学。基于MOF的材料是一个合成平台，可以很好地缓解这些问题。这篇评论突出了李的三个基本功能S电池并根据这些功能对最近开发的基于MOF的材料进行分类。这种基于功能的分类所确定的设计原则为合理设计用于高级LiS电池的基于MOF的材料提供了指导和观点。