A mild, oxidative fluorination approach to a variety of fluorinated phosphorus compounds using trichloroisocyanuric acid (TCICA) and KF was developed as a complement to a recent study on deoxygenative fluorination using oxalyl chloride. Herein, the syntheses of several fluorinated organophosphorus compounds are reported, and both TCICA/KF and oxalyl chloride/KF conditions are compared and contrasted throughout. Initial investigations of the method on other group 15 heteroatoms (i. e., As, Sb, and Bi) are also reported, with varied success. This work notably extends the known TCICA/KF reactivity series to another group of elements beyond previously studied chalcogens (S, Se, and Te) and halogens (iodine) and expands the utility of the previously reported oxalyl chloride/KF method.

中文翻译：

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在第15组杂原子氟化的补充方法中检查三氯异氰尿酸和草酰氯

开发了使用三氯异氰尿酸（TCICA）和KF对多种氟化磷化合物进行轻度氧化氧化的方法，以补充最近对草酰氯进行脱氧氟化的研究。在本文中，报道了几种氟化有机磷化合物的合成，并且对TCICA / KF和草酰氯/ KF条件进行了比较和对比。还报道了对该方法的其他15族杂原子（即As，Sb和Bi）的初步研究，并获得了不同的成功。这项工作尤其将已知的TCICA / KF反应性系列扩展到了先前研究的硫族元素（S，Se和Te）和卤素（碘）之外的另一组元素，并扩展了先前报道的草酰氯/ KF方法的实用性。