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Enhanced safety electrolyte mixture of ionic liquids and lithium salt for Li-ion transference number (Li-T) in Li-Li symmetric coin cell
Inorganic and Nano-Metal Chemistry ( IF 1.7 ) Pub Date : 2020-12-17
T. V. M. Sreekanth, J. Kim, K. Yoo

Abstract

In lithium-ion batteries (LiBs), electrolyte plays an essential role in leading the performance of the cell. Room-temperature (RT) ionic liquids (ILs) are currently the utmost attractive research in the area of LiBs, owing to their intrinsic properties, like low volatility, non-flammability, good thermal stability, and electrochemically stable. In this present study, we report the electrochemical characterization of neat organic, neat ILs, and mixture of organic-ILs (1-Methyl-1-propylpyrrolidinum Bis (Trifluoromethanesulfonyl) Imide (MPPY+TFSI-)). An extensive molarity range has been examined to identify lithium transference numbers (LI-T) associated with symmetrical Li | electrolyte | Li cell. The safety test was performed using symmetrical Li | electrolyte | Li cell for prepared electrolytes.



中文翻译:

锂-锂对称纽扣电池中离子液体和锂盐的增强安全性电解质混合物对锂离子转移数(Li-T)的影响

摘要

在锂离子电池(LiB)中,电解质在领导电池性能方面起着至关重要的作用。室温(RT)离子液体(ILs)由于其固有的特性(如低挥发性,不易燃性,良好的热稳定性和电化学稳定性),在LiBs领域目前是最有吸引力的研究。在本研究中,我们报告纯有机,整齐离子液体的有机离子液体电化学表征和混合物(1-甲基-1- propylpyrrolidinum双(三氟甲烷磺酰)亚胺(MPPY + TFSI - ))。已检查了广泛的摩尔浓度范围,以确定锂转移数 LI-T 与对称李相关| 电解质| 锂电池。安全测试是使用对称Li | 电解质| 用于制备电解液的锂电池。

更新日期:2020-12-17
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