Pre‐organized adaptive Cu(I) bimetallic precursors can be successfully engaged in coordination‐driven supramolecular reactions. Selective formation either of a large family of compact metallacycles or of polymetallic discrete assemblies and one‐dimensional coordination polymers is rationalized taking into account the relative amplitudes of conformational flexibility allowed by the precursors used. It reveals the originality of the self‐assembly processes conducted with such Cu(I)‐based building blocks. In addition, exalted luminescence properties can be embedded in the resulting supramolecular assemblies due to the specific photophysical behaviors of Cu(I)‐luminophores. General and straightforward access toward coordination‐driven supramolecular assemblies featuring original architectures and multifunctional luminescence properties is therefore highlighted, taking advantage of both the specificities of the coordination chemistry and the electronic structure of derivatives based on the Cu(I) ion.

中文翻译：

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基于双金属Cu（I）前体的配位驱动超分子合成：自适应行为和发光。

预组织的自适应Cu（I）双金属前体可以成功地参与配位驱动的超分子反应。考虑到所使用的前体所允许的构象柔韧性的相对幅度，合理化了大批紧凑型金属环摩托车或多金属离散装配体和一维配位聚合物的选择性形成。它揭示了使用此类基于Cu（I）的构建基块进行自组装过程的独创性。此外，由于Cu（I）-荧光团的特定光物理行为，可以将超高的发光特性嵌入到最终的超分子装配中。