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Preparation of low-cost activated carbons from amazonian nutshells for CO2 storage
Biomass & Bioenergy ( IF 6 ) Pub Date : 2020-12-16 , DOI: 10.1016/j.biombioe.2020.105925
Jarosław Serafin , Mohammed Ouzzine , Orlando F. Cruz Junior , Joanna Sreńscek-Nazzal

Low-cost carbonaceous adsorbents with microporous structures and a moderate specific surface area (up to 1630 m2 g−1) were prepared from different amazonian nutshells by one-step chemical activation with KOH for CO2 storage. In-depth micropore structure analysis and surface characterization were performed using adsorption isotherms at 298 K and carbon dioxide isotherms at 273 K. The Brazilian nutshell and Cascara Capuassau exhibit a remarkable CO2 uptake capacity of 5.14 mmol g−1 and 5.13 mmol g−1 at 273 K, respectively up to 1 atm. The highest CO2 adsorption at 298 K equal to 3.67 mmol g−1 was observed on activated carbon produced from Cascara Capuassau. The low-pressure CO2 capacities are well correlated with the volume of small micropores (<0.7 nm) rather than the total micropore volume and surface area. The great mesoporosity of activated carbons is beneficial to ensure higher CO2 capture at high uptake pressure.



中文翻译:

用亚马逊坚果壳制备低成本活性炭,用于CO 2储存

通过使用KOH一步化学活化CO 2储存,由不同的亚马逊坚果壳制备了具有微孔结构和中等比表面积(高达1630 m 2  g -1)的低成本碳质吸附剂。使用298 K的吸附等温线和273 K的二氧化碳等温线进行了深入的微孔结构分析和表面表征。巴西坚果壳和Cascara Capuassau的CO 2吸收能力分别为5.14 mmol g -1和5.13 mmol g -1在273 K下分别达到1 atm。298 K时最高的CO 2吸附量等于3.67 mmol g -1在由卡斯卡拉·卡普阿索(Cascara Capuassau)产生的活性炭上观察到。低压CO 2的容量与小微孔(<0.7 nm)的体积而不是总微孔的体积和表面积密切相关。活性炭的大介孔率有利于确保在高吸收压力下捕获更高的CO 2

更新日期:2020-12-16
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