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Preparation of cigarette butts/coal‐based porous carbon and its catalytic methane decomposition to hydrogen
Asia-Pacific Journal of Chemical Engineering ( IF 1.8 ) Pub Date : 2020-12-14 , DOI: 10.1002/apj.2613
Huafeng Luo 1, 2 , Tongda Li 1 , Yuandong Qiao 1 , Zhangxuan Ning 1 , Chunli Bo 1
Affiliation  

A new type of cigarette butts/coal‐based composite porous carbon was prepared by potassium hydroxide chemical activation method and used for methane decomposition to hydrogen. The effects of mass mixing ratio of the used cigarette butts/coal and carbonization temperature on the surface properties and structure of carbon materials were studied. The results show that the optimal mass mixing ratio of cigarette butts/coal is 1:3, and the increase in temperature can promote the specific surface area of carbon materials from 1850 to 2785 m2/g, the distribution of pore size is also changed from a large number of micropores to mesopores, and the structure became more disordered. DT/YT‐3‐1023 has the highest initial activity, DT/YT‐3‐1123 has the highest stability, and a certain amount of carbon fibers are deposited on the surface of carbon materials after the reaction.

中文翻译:

烟头/煤基多孔碳的制备及其甲烷分解为氢的催化作用

通过氢氧化钾化学活化法制备了一种新型的烟头/煤基复合多孔碳,并将其用于甲烷分解为氢。研究了用过的烟头/煤的质量混合比和碳化温度对碳材料表面性能和结构的影响。结果表明,烟头/煤的最佳混合比为1:3,温度的升高可将碳材料的比表面积从1850提高到2785 m 2。/ g,孔径的分布也从大量的微孔变为中孔,并且结构变得更加无序。DT / YT-3-1023的初始活性最高,DT / YT-3-1123的稳定性最高,反应后一定数量的碳纤维沉积在碳材料的表面。
更新日期:2020-12-14
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