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Structural and dielectric properties of cobalt ferrite based nanocomposites
Physica B: Condensed Matter ( IF 2.8 ) Pub Date : 2020-12-13 , DOI: 10.1016/j.physb.2020.412752
Kalyani Dhabekar , K. Mohan Kant

Nanocomposites of cobalt ferrite (CoFe2O4) were synthesized using chemical co-precipitation route. For preparing the nanocomposites, cobalt ferrite was combined with strontium ferrite (C/S-1/1) and with barium ferrite (C/B-1/1) in equal weight ratio of 1:1. Dual phase Rietveld refinement procedure was employed for phase analysis of the specimens. Electrical transport properties were investigated within frequency scale 20 Hz–106 Hz at different temperatures ranging from 100 °C to 400 °C. Dielectric permittivity of the composites was found to increase with temperature. Polarization mechanism was attributed to Koop's theory due to the presence of conductive and non-conductive part in ferrite composites. The ac conductivity mechanism in the composites was ascribed to Maxwell-Wagner model. With increase in temperature, C/S-1/1 depicts greater conductivity compared to C/B-1/1.



中文翻译:

钴铁氧体基纳米复合材料的结构和介电性能

采用化学共沉淀法合成了钴铁氧体纳米复合材料(CoFe 2 O 4)。为了制备纳米复合材料,将钴铁氧体与锶铁氧体(C / S-1 / 1)和钡铁氧体(C / B-1 / 1)混合,重量比为1:1。采用双相Rietveld精炼程序对样品进行相分析。 在100 Hz至400°C的不同温度下,在20 Hz–10 6 Hz频率范围内研究了电传输特性。发现复合材料的介电常数随温度增加。由于铁氧体复合材料中存在导电和非导电部分,因此极化机制归因于Koop理论。该交流复合材料的电导率机理归因于Maxwell-Wagner模型。随着温度的升高,与C / B-1 / 1相比,C / S-1 / 1的导电性更高。

更新日期:2021-01-02
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