The affinity of Samarium(II) to coordinate with trivalent nitrogen leads to a pre‐association complex prior to the electron transfer. This pre‐association turns out to be extremely effective in terms of enhancing the rate of reduction of substrates with trivalent nitrogen in rather unprecedented mechanistic pathway. This minireview describes these intriguing findings.

中文翻译：

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二碘化Sa还原三价氮化合物的机械机理

mar（II）与三价氮配位的亲和力导致电子转移之前发生预缔合络合物。这种预缔合在以前所未有的机理途径提高三价氮对底物的还原速率方面非常有效。这份迷你评论描述了这些有趣的发现。