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Phase equilibria of the Al2O3–CaO–SiO2-(0%, 5%, 10%) MgO slag system for non-metallic inclusions control
Calphad ( IF 2.4 ) Pub Date : 2020-12-08 , DOI: 10.1016/j.calphad.2020.102227
Zan Yao , Xiaodong Ma , Sha Lyu

Al2O3–CaO-(MgO–SiO2) inclusions are one of the dominant inclusions in Al-deoxidized spring steel, the compositions changes of which are closely related to refining slags and deoxidization process. The Al2O3–CaO–SiO2–MgO system can represent the primary ingredients of the Al2O3–CaO inclusions. According to analyzed compositions and predicted liquidus temperature ranges of inclusions and refining slag, equilibra experiments under high temperature, water quenching technique and subsquent electron probe X-ray microanalysis (EPMA) has been conducted to ascertain detailed thermodynamic database for inclusions control. Liquidus temperatures within the dominant phase fields of Ca3SiO5, Ca2SiO4, CaAl2O4, Ca3Al4O9, spinel and MgO with the intervals of 20 °C from 1350 to 1560°C were identified. To further promote inclusions control, the influences of mass ratios of Mass(Al2O3)Mass(Al2O3+SiO2+CaO) and MgO contents on equilibrated phases and liquidus temperature changes have been explored. To further enhance modification levels of Al2O3–CaO-(MgO–SiO2) system inclusions, it is suggested that refining time could be suitably prolonged.



中文翻译:

用于非金属夹杂物控制的Al 2 O 3 -CaO-SiO 2-(0%,5%,10%)MgO炉渣系统的相平衡

Al 2 O 3 -CaO-(MgO-SiO 2)夹杂物是Al脱氧弹簧钢中的主要夹杂物之一,其成分变化与精炼渣和脱氧过程密切相关。Al 2 O 3 -CaO-SiO 2 -MgO体系可以代表Al 2 O 3的主要成分–CaO夹杂物。根据夹杂物和精炼炉渣的成分分析和预测的液相线温度范围,进行了高温下的平衡实验,水淬技术和随后的电子探针X射线显微分析(EPMA),以确定用于夹杂物控制的详细热力学数据库。Ca 3 SiO 5,Ca 2 SiO 4,CaAl 2 O 4,Ca 3 Al 4 O 9的主相场中的液相线温度鉴定出尖晶石和MgO在1350至1560°C之间的间隔为20°C。为了进一步促进夹杂物的控制,探索了质量比(Al2O3)质量(Al2O3 + SiO2 + CaO)和MgO的质量比对平衡相和液相线温度变化的影响。为了进一步提高Al 2 O 3 -CaO-(MgO-SiO 2)系统夹杂物的改性水平,建议可以适当延长精炼时间。

更新日期:2020-12-08
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