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Synthesis and Characterization of Nitrogen Subvalence in a Pt Metallonitrene
Trends in Chemistry ( IF 15.7 ) Pub Date : 2020-12-07 , DOI: 10.1016/j.trechm.2020.11.005
Debabrata Sengupta , David C. Powers

Late-metal–ligand multiply bonded complexes are typically highly reactive species and are proposed intermediates in a variety of catalytic bond activations. Using spectroscopic, theoretical, and in situ photocrystallographic tools, Holthausen, Schneider, et al. report the first bona fide metallonitrene complex and illuminate structure-activity relationships critical to catalyst development.



中文翻译:

Pt金属铝中氮取代度的合成与表征

后期金属-配体多重键合络合物通常是高反应性物质,被提议为各种催化键活化的中间体。Holthausen,Schneider等人使用光谱学,理论和原位光晶体学工具报告了第一个真正的金属茂复合物,并阐明了对催化剂开发至关重要的结构-活性关系。

更新日期:2020-12-07
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